| ROUND | R1 | R2 | QF | SF | ||||
| r1 | r2 | r3 | r4 | r5 | ||||
| Season archive | 
| Group A | Overall | |||||||||||
| P | W | D | L | F | A | Gdf | Pts | Form | ||||
| 1 | Falkirk | 1 | 1 | 0 | 0 | 7 | 0 | +7 | 3 | W--- | ||
| 2 | 2 | Queen's Park | 2 | 1 | 0 | 1 | 6 | 2 | +4 | 3 | WL-- | |
| 3 | Cove Rangers | 1 | 1 | 0 | 0 | 1 | 0 | +1 | 3 | W--- | ||
| 4 | 2 | Spartans | 2 | 1 | 0 | 1 | 2 | 2 | +0 | 3 | LW-- | |
| 5 | Brechin City | 2 | 0 | 0 | 2 | 0 | 12 | -12 | 0 | LL-- | ||
| Tuesday, 15 July 2025 | |||||
| 2 | Queen's Park | 5-0 | Brechin City | ||
| 13 | McDonnell | ||||
| 46 | Fowler | ||||
| 55 | Fowler | ||||
| 60 | McDonnell | ||||
| 70 | Ruth | ||||
| 2 | Cove Rangers | 1-0 | Spartans | ||
| 4 | Glass | ||||
| Group B | Overall | |||||||||||
| P | W | D | L | F | A | Gdf | Pts | Form | ||||
| 1 | Partick Thistle | 2 | 2 | 0 | 0 | 6 | 1 | +5 | 6 | WW-- | ||
| 2 | 2 | Queen of the South | 1 | 1 | 0 | 0 | 4 | 0 | +4 | 3 | W--- | |
| 3 | 1 | Stranraer | 2 | 0 | 1 | 1 | 1 | 3 | -2 | 2 | LX-- | |
| 4 | 1 | Ross County | 1 | 0 | 1 | 0 | 1 | 1 | +0 | 1 | X--- | |
| 5 | Edinburgh City | 2 | 0 | 0 | 2 | 1 | 8 | -7 | 0 | LL-- | ||
| Tuesday, 15 July 2025 | |||||
| 2 | Partick Thistle | 2-0 | Stranraer | ||
| 45+2 | Ashcroft | ||||
| 88 | Watt | ||||
| 2 | Queen of the South | 4-0 | Edinburgh City | ||
| 16 | Guthrie | ||||
| 46 | Lyon | ||||
| 51 | Lyon | ||||
| 78 | Hewitt | ||||
| Group C | Overall | |||||||||||
| P | W | D | L | F | A | Gdf | Pts | Form | ||||
| 1 | Airdrieonians | 2 | 2 | 0 | 0 | 4 | 0 | +4 | 6 | WW-- | ||
| 2 | Alloa Athletic | 2 | 2 | 0 | 0 | 3 | 1 | +2 | 6 | WW-- | ||
| 3 | Montrose | 1 | 0 | 0 | 1 | 1 | 2 | -1 | 0 | L--- | ||
| 4 | 1 | Dundee | 1 | 0 | 0 | 1 | 0 | 1 | -1 | 0 | L--- | |
| 5 | 1 | Bonnyrigg Rose | 2 | 0 | 0 | 2 | 0 | 4 | -4 | 0 | LL-- | |
| Tuesday, 15 July 2025 | |||||
| 2 | Airdrieonians | 3-0 | Bonnyrigg Rose | ||
| 11 | Armstrong | ||||
| 38(p) | Henderson | ||||
| 40 | McGrattan | ||||
| 2 | Alloa Athletic | 2-1 | Montrose | ||
| 21 | O'Donnell | 57 | Waddell | ||
| 61 | Roberts | ||||
| Group D | Overall | |||||||||||
| P | W | D | L | F | A | Gdf | Pts | Form | ||||
| 1 | 3 | St.Mirren | 2 | 1 | 1 | 0 | 2 | 1 | +1 | 4 | WO-- | |
| 2 | 3 | Ayr United | 1 | 1 | 0 | 0 | 6 | 1 | +5 | 3 | W--- | |
| 3 | 1 | Arbroath | 1 | 0 | 1 | 0 | 0 | 0 | +0 | 2 | O--- | |
| 4 | 3 | Forfar Athletic | 2 | 0 | 1 | 1 | 2 | 3 | -1 | 2 | LX-- | |
| 5 | 2 | Annan Athletic | 2 | 0 | 1 | 1 | 2 | 7 | -5 | 1 | LX-- | |
| Tuesday, 15 July 2025 | |||||
| 2 | Forfar Athletic | 1-2 | St.Mirren | ||
| 80 | Inglis | 9 | Richardson | ||
| 75 | Mandron | ||||
| 2 | Annan Athletic | 1-6 | Ayr United | ||
| 70 | Smith | 16 | Walker | ||
| 41 | Oakley | ||||
| 46 | Oakley | ||||
| 47 | Oakley | ||||
| 60 | Thomas | ||||
| 75 | McRoberts | ||||
| Group E | Overall | |||||||||||
| P | W | D | L | F | A | Gdf | Pts | Form | ||||
| 1 | Hearts | 2 | 2 | 0 | 0 | 8 | 1 | +7 | 6 | WW-- | ||
| 2 | 1 | Dumbarton | 1 | 1 | 0 | 0 | 1 | 0 | +1 | 3 | W--- | |
| 3 | 1 | Hamilton | 2 | 1 | 0 | 1 | 2 | 4 | -2 | 3 | LW-- | |
| 4 | 1 | Dunfermline | 1 | 0 | 0 | 1 | 1 | 4 | -3 | 0 | L--- | |
| 5 | 1 | Stirling Albion | 2 | 0 | 0 | 2 | 0 | 3 | -3 | 0 | LL-- | |
| Tuesday, 15 July 2025 | |||||
| 2 | Hamilton | 0-4 | Hearts | ||
| 6 | Findlay | ||||
| 45+1 | Kabangu | ||||
| 69 | Wilson | ||||
| 83 | Cláudio Braga | ||||
| 2 | Dumbarton | 1-0 | Stirling Albion | ||
| 53(og) | Banner | ||||
| Group G | Overall | |||||||||||
| P | W | D | L | F | A | Gdf | Pts | Form | ||||
| 1 | Morton | 2 | 2 | 0 | 0 | 7 | 2 | +5 | 6 | WW-- | ||
| 2 | Motherwell | 2 | 1 | 1 | 0 | 4 | 3 | +1 | 5 | WX-- | ||
| 3 | Clyde | 1 | 0 | 1 | 0 | 2 | 2 | +0 | 1 | X--- | ||
| 4 | 1 | Peterhead | 2 | 0 | 0 | 2 | 3 | 6 | -3 | 0 | LL-- | |
| 5 | 1 | Stenhousemuir | 1 | 0 | 0 | 1 | 0 | 3 | -3 | 0 | L--- | |
| Tuesday, 15 July 2025 | |||||
| 2 | Motherwell | 2-1 | Peterhead | ||
| 28 | Longelo | 9 | Brown | ||
| 90+1 | Fadinger | ||||
| 2 | Morton | 3-0 | Stenhousemuir | ||
| 7 | Adeloye | ||||
| 43 | Moffat | ||||
| 45+3 | Adeloye | ||||
| Group H | Overall | |||||||||||
| P | W | D | L | F | A | Gdf | Pts | Form | ||||
| 1 | Kilmarnock | 2 | 2 | 0 | 0 | 3 | 0 | +3 | 6 | WW-- | ||
| 2 | 1 | Kelty Hearts | 1 | 1 | 0 | 0 | 4 | 0 | +4 | 3 | W--- | |
| 3 | 1 | Livingston | 2 | 1 | 0 | 1 | 2 | 2 | +0 | 3 | LW-- | |
| 4 | East Fife | 1 | 0 | 0 | 1 | 1 | 2 | -1 | 0 | L--- | ||
| 5 | Brora Rangers | 2 | 0 | 0 | 2 | 0 | 6 | -6 | 0 | LL-- | ||
| Tuesday, 15 July 2025 | |||||
| 2 | Brora Rangers | 0-4 | Kelty Hearts | ||
| 3 | Johnston | ||||
| 14 | Cole | ||||
| 45+2 | Cole | ||||
| 64 | Ferguson | ||||
| Wednesday, 16 July 2025 | |||||
| 2 | Kilmarnock | 1-0 | Livingston | ||
| 31(og) | Sylla | ||||
| 4 | John ROBERTSON (East Kilbride) | |
| 3 | +2 | Josh FOWLER (Queen's Park) | 
| Dylan TAIT (Falkirk) | ||
| +3 | George OAKLEY (Ayr United) | |
| 2 | +1 | Aidan SMITH (Annan Athletic) | 
| +2 | Tomi ADELOYE (Morton) | |
| Dylan EASTON (Raith Rovers) | ||
| +1 | James WILSON (Hearts) | |
| +2 | Tyrece McDONNELL (Queen's Park) | |
| Jai ROWE (Raith Rovers) | ||
| Lewis VAUGHAN (Raith Rovers) | ||
| Tawanda MASWANHISE (Motherwell) | ||
| +2 | Robbie COLE (Kelty Hearts) | |
| Lawrence SHANKLAND (Hearts) | ||
| +2 | Reece LYON (Queen of the South) | |
| Scott ARFIELD (Falkirk) |