Brazil
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| Match dates |
| Friday, 13 June 2014 | |||||
| Chile | 3-1 | Australia | |||
| Spain | 1-5 | Netherlands | |||
| Wednesday, 18 June 2014 | |||||
| Australia | 2-3 | Netherlands | |||
| Spain | 0-2 | Chile | |||
| Monday, 23 June 2014 | |||||
| Australia | 0-3 | Spain | |||
| Netherlands | 2-0 | Chile | |||
| Group B | Overall | |||||||||||
| P | W | D | L | F | A | Gdf | Pts | Form | ||||
| 1 |  Netherlands | 3 | 3 | 0 | 0 | 10 | 3 | +7 | 9 | WWW- | ||
| 2 |  Chile | 3 | 2 | 0 | 1 | 5 | 3 | +2 | 6 | LWW- | ||
| 3 |  Spain | 3 | 1 | 0 | 2 | 4 | 7 | -3 | 3 | WLL- | ||
| 4 |  Australia | 3 | 0 | 0 | 3 | 3 | 9 | -6 | 0 | LLL- | ||
| 3 | Robin VAN PERSIE (Netherlands) |
| Arjen ROBBEN (Netherlands) | |
| 2 | Memphis DEPAY (Netherlands) |
| Tim CAHILL (Australia) | |
| 1 | Alexis SÁNCHEZ (Chile) |
| Jorge VALDIVIA (Chile) | |
| David VILLA (Spain) | |
| Charles ARÁNGUIZ (Chile) | |
| Mile JEDINAK (Australia, 1p) | |
| Fernando TORRES (Spain) | |
| Eduardo VARGAS (Chile) | |
| Stefan DE VRIJ (Netherlands) | |
| Jean BEAUSÉJOUR (Chile) | |
| Juan MATA (Spain) | |
| Leroy FER (Netherlands) | |
| XABI ALONSO (Spain, 1p) |
